Unveiling the power of hot carriers in plasmonic nanostructures

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CPLAS Principal Investigator Anatoly Zayats has published a scientific review in eLight that unveils the remarkable the remarkable potential of hot carriers and how they could revolutionise technology across multiple fields. The article was published alongside colleagues from Johns Hopkins University.

Hot carriers are electrons with excess energy, created when light interacts with specially designed nanostructures. This interaction pushes the electrons into a high-energy, non-equilibrium state, unlocking a range of fascinating possibilities. The review highlights several exciting potential applications for hot carriers, including advanced light-based technologies, enhanced photocatalysis, and ultrafast electronics.

One of the most intriguing aspects of hot carriers is their ability to manipulate light itself, potentially leading to the development of advanced optical devices. These energetic electrons can also drive chemical reactions at the nanostructure’s surface, which could significantly boost efficiency in various chemical processes.  Additionally, the generation of electrical currents from hot carriers could pave the way for next-generation, high-speed detectors and optoelectronic devices.

Inter-relations between hot-electron processes

Zayats’ review provides an in-depth exploration of hot carrier behaviour in plasmonic nanostructures. It delves into the mechanics of hot carrier generation through light interaction, examines the energy dissipation processes as hot carriers return to equilibrium, and discusses methods for controlling hot carrier dynamics for specific applications. This comprehensive analysis lays the groundwork for future research and development in this promising field.The potential applications of hot carrier technology are far-reaching and could transform multiple industries. In the realm of electronics, hot carriers could enable the creation of ultrafast devices that operate at speeds previously thought impossible. In the energy sector, they could significantly improve solar cell efficiency, helping to address global energy challenges. Hot carriers have the potential to revolutionise nanomedicine by allowing for precise control at the molecular level, opening up new possibilities for targeted treatments and diagnostics

As scientists continue to unravel the mysteries of these energetic electrons, we may be on the cusp of a new era of light-controlled, nanostructure-based innovations. Zayats’ review paints a future in which the manipulation of light at the nanoscale could lead to transformative technologies across a wide range of fields, potentially reshaping our technological landscape in the years to come.

You can read the review in eLight

Hot-electron dynamics in plasmonic nanostructures: fundamentals, applications and overlooked aspects.
Khurgin, J., Bykov, A.Y. & Zayats, A.V. eLight 4, 15 (2024)
DOI:  10.1186/s43593-024-00070-w